Inside Back Cover: Ru V ‐Acylimido Intermediate in [Ru IV (Por)Cl 2 ]‐Catalyzed C–N Bond Formation: Spectroscopic Characterization, Reactivity, and Catalytic Reactions (Angew. Chem. Int. Ed. 34/2021)
نویسندگان
چکیده
Metal-catalyzed acylnitrene transfer reactions are widely proposed to proceed via M(NCOR) intermediates. In their Research Article on page 18619, Chi-Ming Che and co-workers report [Ru(Por)Cl2]-catalyzed highly selective transfers alkenes, indoles, silyl enol ethers, C(sp3)−H bonds afford aziridines/oxazolines, 3-aminoindoles, α-aminoketones, N-acyl amines, respectively, also experimental computational evidence that porphyrin-supported Ru(NCOR) intermediates, which belong RuV-imido species, involved in these reactions.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/anie.202107753